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6. Main-Group and Descriptive Chemistry

  • Periodic trends & oxidation states: Variation across groups and periods; inert-pair effect, relativistic effects in heavy elements.
  • p-block chemistry: Multiple bonding (double/triple bonds), hypervalency, cage molecules (boranes, carboranes), allotropes (carbon, phosphorus, sulfur).
  • s- and f-block elements: Lanthanide contraction and chemistry, actinide electronic structure, common oxidation states and coordination behavior; f-orbital participation and spectroscopy.

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Book Title: Advanced Inorganic Chemistry

Author: R.D. Madan


Exam Preparation: Popular for competitive exams like NEET and JEE due to its clear presentation, solved examples, and extensive question banks (nearly 900 multiple-choice questions). Access and "Free" PDF Availability Advanced Inorganic Chemistry by RD Madan PDF Free

Part I: Basic Concepts and Atomic Structure

Unit 1: Atomic Structure and Wave Mechanics Periodic trends & oxidation states: Variation across groups

  • Bohr’s Theory and its limitations.
  • Introduction to Quantum Mechanics: de Broglie equation, Heisenberg’s Uncertainty Principle.
  • Schrödinger Wave Equation (Basic concepts).
  • Quantum Numbers and their significance.
  • Shapes of s, p, d, and f orbitals.
  • Pauli’s Exclusion Principle, Hund’s Rule, and Aufbau Principle.
  • Electronic configuration of elements.
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