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6. Main-Group and Descriptive Chemistry
- Periodic trends & oxidation states: Variation across groups and periods; inert-pair effect, relativistic effects in heavy elements.
- p-block chemistry: Multiple bonding (double/triple bonds), hypervalency, cage molecules (boranes, carboranes), allotropes (carbon, phosphorus, sulfur).
- s- and f-block elements: Lanthanide contraction and chemistry, actinide electronic structure, common oxidation states and coordination behavior; f-orbital participation and spectroscopy.
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Book Title: Advanced Inorganic Chemistry
Author: R.D. Madan
Exam Preparation: Popular for competitive exams like NEET and JEE due to its clear presentation, solved examples, and extensive question banks (nearly 900 multiple-choice questions). Access and "Free" PDF Availability Advanced Inorganic Chemistry by RD Madan PDF Free
Part I: Basic Concepts and Atomic Structure
Unit 1: Atomic Structure and Wave Mechanics Periodic trends & oxidation states: Variation across groups
- Bohr’s Theory and its limitations.
- Introduction to Quantum Mechanics: de Broglie equation, Heisenberg’s Uncertainty Principle.
- Schrödinger Wave Equation (Basic concepts).
- Quantum Numbers and their significance.
- Shapes of s, p, d, and f orbitals.
- Pauli’s Exclusion Principle, Hund’s Rule, and Aufbau Principle.
- Electronic configuration of elements.


